A Station Eight Fan Web Site
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Were Barbara and Dick each others' first kisses?
For Barbara, yes.
For Dick, well, I guess it depends on how you're defining "first kiss". But Dick and Barbara's kiss in issue #25 of the comic takes place before Dick and Zatanna's kiss in episode 126 of the series. But Zatanna kissed Dick earlier then either of those two kisses in issue #20 of the comic. But it was basically just a peck, so I don't know if you'd count that.